文章摘要
Properties of PEG/PLA/ENR TPV
Received:December 04, 2020  Revised:December 04, 2020
DOI:10.12136/j.issn.1000-890X.2021.04.0249
Key Words: PLA;ENR;PEG;TPV;bio-based;dynamic vulcanization;toughening
Author NameAffiliationE-mail
JIANG Gang* South China University of Technology jpding@scut.edu.cn 
CHEN Yukun South China University of Technology  
DING Jianping South China University of Technology  
FANG Yuesheng South China University of Technology  
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Abstract:
      The properties of polyethylene glycol(PEG)/polylactic acid(PLA)/epoxidized natural rubber(ENR) thermoplastic vulcanizate(TPV) prepared via dynamic vulcanization were studied.The results showed that PEG exhibited excellent effect on TPV.With the increasing of PEG amount,the elongation at break and impact strength of TPV increased significantly,when PEG amount was 10 phr,the elongation at break increased from 16% to 321%,and the impact strength increased from 30.6 kJ·m-2 to 53.6 kJ·m-2.Meanwhile,the tensile strength,tensile modulus and bending strength of the TPV decreased to some extent.The PEG was mainly distributed in the PLA matrix,and the PEG could greatly reduce the glass transition temperature of PLA and improve its crystallization ability.The TPV produced plastic deformation along the stress direction during the stretching process.
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