Reinforcement of vulcanized NBR by in-situ polymerized sodium methylacrylate |
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DOI: |
Key Words: sodium methylacrylate;in-situ polymerization;nano-composite |
Author Name | Affiliation | JIAO Hai-quan | Beijing University of Chemical Technology | ZHAO Su-he | Beijing University of Chemical Technology | YUAN Wei | Beijing University of Chemical Technology |
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Abstract: |
The nano-composites of in-situ polymerized sodium methylacrylate(PNaMAA)/NBR were prepared and the effects of the mixing procedure,the level of DCP,the molecular ratio of MAA/sodium hydroxide and the theoretical yield of NaMAA on the physical properties of composites were investigated.The results showed that the PNaMAA/NBR nano-composite with the optimum physical properties was obtained by using 1.5 phr of DCP,MAA/sodium hydroxide with molecular ratio of 1.5:1,30 phr of NaMAA for theoretical yield,160 ℃×t90 cure and mixing procedure,in which the acid was rapidly added at first,and the alkali was added in batches later. |
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