| Preparation of aromatic hydrocarbon-free and self-crosslinking CR/SBS/MMA/BA adhesive for shoes |
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| DOI： |
| Key Words: CR；SBS；NMA；BA；self-crosslinking；adhesive for shoes |
| Author Name | Affiliation | | ZHANG Dong-liang | Jiangsu Institute of Petrochemical Technology | | TANG Wei-feng | Jiangsu Institute of Petrochemical Technology | | YANG Huai | Jiangsu Institute of Petrochemical Technology |
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| Abstract: |
| A polybasic graft copolymerization of acrylic acid （AA）and N-（hydroxymethy l）acrylamide（NAM）as functional monomers with methy l methacrylate（MMA），butyl acrylate（BA）on CR and SBS was carried out in an aromatic hydrocarbon-free solvent by using composite initiator.An aromatic hydrocarbon-free solvent and self-crosslinking adhesive for shoes was prepared with the above copolymer by adding a tackifying resin.The influence of the addition levels of SBS，NAM and AA，and the MMA/BA ratio on the adhesive properties was investigated.The results showed that the properties of the above said adhesive bonded to non-polar shoe materials were much better than those of both CR/MMA/BA terbasic graft copolymer adhesive and CR/SBS/MMA/BA tetrabasic graft copolymer adhesive. |
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