文章摘要
Influence of Antioxidant Types on Seawater Aging Resistance of CR Compouds and Its Aging Mechanism
Received:January 06, 2025  Revised:January 06, 2025
DOI:10.12136/j.issn.1000-890X.2026.06.0425
Key Words: CR;seawater aging resistance;amine antioxidants;high molecular weight antioxidant;reactive antioxidant
Author NameAffiliationE-mail
LIU Quanzhong North Huajin Chemical Industries Co.,Ltd 1298550450@qq.com 
YAO Xiuchao* North Huajin Chemical Industries Co.,Ltd yaoxiuchao87@163.com 
HAO Chunbo North Huajin Chemical Industries Co.,Ltd  
LI Chunhui North Huajin Chemical Industries Co.,Ltd  
WANG Chun North Huajin Chemical Industries Co.,Ltd  
JIANG Cui North Huajin Chemical Industries Co.,Ltd  
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Abstract:
      The influence of antioxidant types on the seawater aging resistance of chloroprene rubber(CR) compounds and its aging mechanism were studied.The results showed that during deep-sea environment immersion(deep-sea aging) process,the antioxidant of CR compound migrated and precipitated ,leading to a rapid decline in the aging resistance of CR compound.The antioxidant in CR compound was essentially eliminated after aging in deep-sea for 3 a.Compared to CR compound prepared with amine antioxidant 4020,the Shore A hardness,tensile strength and elongation at break of CR compound prepared with high molecular weight antioxidants TNPP/TH-1790 blend or high molecular weight antioxidants(TNPP and TH-1790)/reactive antioxidant BZ20 blend increased.The physical properties of CR compound prepared with high molecular weight antioxidants(TNPP and TH-1790)/ reactive antioxidant BZ20 blend were optimal,and the seawater aging resistance was the best.
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