文章摘要
Study on Peroxide Curing Systerm of HNBR Compound
Received:March 31, 2021  Revised:March 31, 2021
DOI:10.12136/j.issn.1000-890X.2022.02.0115
Key Words: HNBR;peroxide curing system;compression set;heat-oxygen aging resistance;oil resistance
Author NameAffiliationE-mail
WANG Leilei* SINOPEC Beijing Research Institute of Chemical Industry Yanshan Branch/National Engineering Research Center for Synthesis of Novel Rubber and Plastic Materials wangll.bjhy@sinopec.com 
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Abstract:
      The effects of the amounts of curing agent DCP and cocrosslinking agent TAC on the properties of hydrogenated nitrile rubber(HNBR) compound were studied. The results showed that when the amount of cocrosslinking agent TAC was 3 phr,with the increase of the amount of curing agent DCP, the scorch time and optimal curing time of HNBR compound were shortened,the physical properties of the vulcanizate were improved,the compression set was significantly reduced,and the heat-oxygen aging resistance was improved. When the amount of curing agent DCP was 4 phr,with the increase of the amount of cocrosslinking agent TAC,the Mooney viscosity of HNBR compound decreased,the modulus of the vulcanizate increased,the compression set decreased,and the heat-oxygen aging resistance changed little. The amounts of curing agent DCP and cocrosslinking agent TAC had a certain effect on the physical properties of HNBR vulcanizate after oil immersion,but had little effect on the volume expansion rate.
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