文章摘要
Application of Interface Coupling Agent KH550 in Graphene Oxide/Silica Nano-hybrid Fillers
Received:September 18, 2018  Revised:September 18, 2018
DOI:10.12136/j.issn.1000-890X.2019.08.0587
Key Words: interface coupling agent;graphene oxide;silica;nano-hybrid filler;SBR;BR;composite;wear resistance;heat build-up
Author NameAffiliationE-mail
LI Pengju Beijing University of Chemical Technology 379614771@qq.com 
WU Xiaohui* Beijing University of Chemical Technology wuxiaohui555@163.com 
LU Yonglai Beijing University of Chemical Technology  
ZHANG Liqun Beijing University of Chemical Technology  
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Abstract:
      The silica was modified by γ-aminopropyltriethoxysilane(coupling agent KH550),then mechanically mixed with the graphene oxide(GO) suspension,and coupling agent KH550 modified GO/Silica nano-hybrid filler(GO@SiO2) was prepared by spray-drying mixture.The effect of the coupling agent KH550 amount on the properties of the solution-polymerized styrene-butadiene rubber(SSBR)/butadiene rubber(BR)/GO@SiO2 composite was investigated.The results showed that,when the mass fraction of coupling agent KH550 was 7% and 10% of silica,the thermal stability of GO@SiO2 was better.The coupling agent KH550 could significantly improve the crosslink density,filler dispersibility,wear resistance and reduce heat build-up of composites.When the mass fraction of coupling agent KH550 was 5% of silica,the crosslink density was the highest and the comprehensive physical properties of the composite were the best.When the mass fraction of coupling agent KH550 was 10% of silica,the wear resistance of the composite was the best and the heat build-up was the lowest.
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