文章摘要
Study on Silica/SBR Composite Modified by Gemini Ionic Liquid
  
DOI:
Key Words: Gemini ionic liquid;SBR;silica;composite;interfacial interaction
Author NameAffiliation
SHEN Zuo-li South China University of Technology 
LEI Yan-da South China University of Technology 
TANG Zheng-hai South China University of Technology 
ZHU Li-xin South China University of Technology 
GUO Bao-chun South China University of Technology 
JIA De-min South China University of Technology 
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Abstract:
      A novel Gemini ionic liquid,bis(1-methylimidazolium) mercaptosuccinate(BMimMS),was synthesized by neutralization of N-methyl imidazole and mercaptosuccinic acid,and the structure of BMimMS was characterized.BMimMS was used as the interfacial modifier for silica/SBR composites,and the filler network,curing behavior,physical properties and morphology of the composite were investigated.The results showed that,the cation and anion of BMimMS formed hydrogen bond with siloxane and silanol of silica,respectively.The crosslink density of silica/SBR composites was increased as the addition level of BMimMS increased,but the dispersion of silica was not obviously improved.BMimMS could effectively strengthen the silica-SBR interfacial interaction,and the physical properties and loss factor in low temperature region(-20~0 ℃) were improved by BMimMS,resulting in improved wet skid resistance.
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