文章摘要
Preparation of Gradient Polymer with Wide Damping Temperature Range by In-situ Sulfur Modification
  
DOI:
Key Words: gradient polymer;SBR;NBR;in-situ sulfur modification;vulcanization;wide temperature range;damping
Author NameAffiliation
WANG SONG Jilin Design Institute, Northeast Refining & Chemical Engineering Co. Ltd 
LIU Qing-sheng Beijing University of Chemical Technology 
WANG Yi-qing Beijing University of Chemical Technology 
WANG Ya Beijing University of Chemical Technology 
ZHANG Li-qun Beijing University of Chemical Technology 
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Abstract:
      By controlling the migration of chemical reaction and diffusion of sulfur concentration in the rubber matrix to form sulfur distribution gradient,gradient polymer with wide damping temperature range was prepared.The results showed that,the glass transition range of SBR gradient polymer was over 100 ℃,and the peak width at half height was 69.44 ℃;the glass transition range of NBR gradient polymer was over 120 ℃,and the half width was 59.4 ℃.
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