文章摘要
Influence of Plasticizing System on Properties of CIIR/PA12 TPV
  
DOI:
Key Words: CIIR;polydodecalactam 12;thermoplastic vulcanizate;plasticizer;rheological behavior;air permeability
Author NameAffiliation
SHI Sha-sha Beijing University of Chemical Technology 
WU She-mao Beijing University of Chemical Technology 
ZHANG Li-qun Beijing University of Chemical Technology 
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Abstract:
      The CIIR/polydodecalactam 12(PA12) thermoplastic vulcanizate(TPV) was prepared by dynamic vulcanization,the influence of naphthenic oil,polyisobutylene and N-butyl benzenesulfonamide on the physical properties,rheological behavior,crystallization,dynamic mechanical properties and air permeability of CIIR/PA12 TPV was investigated.The results showed that N-butyl benzenesulfonamide was effective plastizer of CIIR/PA12 TPV.Compared to naphthenic oil and polyisobutylene,with small amount of N-butyl benzenesulfonamide,the physical properties and air permeability of TPV changed a little,but the hardness was reduced significantly,and the extrudate appearance and processing property were improved.N-butyl benzenesulfonamide had little effect on the crystallization of plastic phase,and the glass transition temperature of PA12 decreased up to 40 ℃.
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