Effects of dynamic tension fatigue on the structure and physical properties of SBR compounds |
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DOI: |
Key Words: SBR;silica;dynamic tension fatigue;cross-link density;physical property;dynamic property |
Author Name | Affiliation | HUANG Yu-hua | Qingdao University of Science and Technology | LIU Ji-wen | Qingdao University of Science and Technology | ZHAO Shu-gao | Qingdao University of Science and Technology | ZHANG Ping | Qingdao University of Science and Technology |
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Abstract: |
The effects of dynamic tension fatigue on the structures and physical properties of unfilled SBR compound and silica-filled SBR compound were investigated.The results showed that the cross-link density of SBR compounds decreased as the number of tension fatigue cycles increased,the cross-link density of silica-filled SBR compound was bigger than that of unfilled SBR compound;the conjugated diene structure was generated at the molecular chain-ends after tension fatigue;when the number of tension fatigue cycles increased,the physical properties of unfilled SBR compound and silica-filled SBR compound increased at first and then decreased;after tension fatigue,the elastic modulus of SBR compounds decreased and the tanδ value in rubbery temperature region increased. |
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