Study on the characteristics of rare earth complex as rubber vulcanization accelerator |
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DOI: |
Key Words: NR;SBR;rare earth complex;accelerator;curing characteristics;dynamic mechanical property |
Author Name | Affiliation | WEI Feng-xian | South China Normal University | ZHANG Wei-guang | South China Normal University | FAN Jun | South China Normal University | YIN Xia | South China Normal University | LIU Xian-feng | South China University of Technology | HUANG Miao-you | South China University of Technology |
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Abstract: |
The N-cyclohexyl-2-benzothiazole sulfenamide neodymium complex was synthesized with accelerator CZ as ligand,and its application in NR/SBR blend was investigated.It was confirmed by element analysis and infra-red spectroscopy analysis that,the composition of the rare earth complex was Nd(CZ)Cl3·Nd(OH)Cl2·H2O. The rare earth complex had a delay characteristic of sulfonamide accelerators and was suitable for vulcanization of thick-walled rubber goods;after heat aging,the Shore A hardness,the modulus at 300% elongation and tear strength of vulcanizate were increased,the tensile strength,elongation at break and tensile set at break of vulcanizate were decreased;the rolling resistance and the heat build-up of tread compound with the rare earth complex could be decreased. |
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