Preparation of nano polymer filler and properties of the filled rubber compound |
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DOI: |
Key Words: emulsion polymerization;nano polymer filler;SBR;NBR |
Author Name | Affiliation | WANG Lian-sheng | Beijing University of Chemical Technology | LU Ming | Beijing University of Chemical Technology | ZHOU Jian-jun | Beijing University of Chemical Technology | ZHAO Wei | Beijing University of Chemical Technology | LIU Ya-kang | Beijing University of Chemical Technology | ZHANG Li-qun | Beijing University of Chemical Technology |
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Abstract: |
Monodisperse crosslinked polystyrene(PS) and α-methyl styrene-acrylonitrile(α-MS-AN) nano-latex particles were prepared by emulsion polymerization,and the physical properties of NBR and SBR filled with nano-latex particles were investigated.The results showed that the average particle size and Tg of PS were 43 nm and 125 ℃ respectively when the addition level of KPS,OP-10,SDS and DVB were 1%,3.3%,6.6% and 20%,respectively;the average particle size and Tg of α-MS-AN were 47 nm and 152 ℃ respectively when the addition level of APS,MS-1 and DVB were 0.3%,2%~3% and 15%,respectively.The optimum addition level of fillers was 30 phr;the physical properties of PS filled SBR was better than those of PS filled NBR;and the physical properties of α-MS-AN filled NBR was better than those of α-MS-AN filled SBR. |
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