Modification of EPDM/MVQ with silane-grafting EPM |
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DOI: |
Key Words: silane-grafting EPM;compatibilizer;EPDM;MVQ;blend;modification |
Author Name | Affiliation | HE Jiang-hong | Beijing Research and Design Institute of Rubber Industry | XIE Zhong-lin | Beijing Research and Design Institute of Rubber Industry |
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Abstract: |
The EPDM/MVQ was modified by using the silane-grafting EPM (EPM-g-S)as the compatibilizer and the modification mechanism was discussed.EPM-g-S was obtained by mixing EPM,silane coupling agent A-174[γ-(methyl acryldeoxy)propyl trimethyl silane] and DCP in a Brabender rheometer at the high temperature (170 ~ 190 ℃) and the high shearing (with rotor speed of 60 ~ 80 r·min-1.The physical properties,particularly the heat resistance and the compression set at high temperature of EPDM/MVQ were improved by using EPM-g-S as compatibilizer.It was found with infrared absorption spect rum that EPM-g-S was the product of the silane coupling agent A-174 grafted on the EPM molecular chain and the covulcanization of EPDM/MVQ or EPDM/EPM-g-S was achieved by peroxide crosslinking agent. |
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