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低顺式聚丁二烯橡胶凝胶产生原因及控制措施
Causes and Control Measures of Gel in Low cis-Polybutadiene Rubber
Received:September 25, 2025  Revised:September 25, 2025
DOI:10.12137/j.issn.2095-5448.2026.07.0394
中文关键词: 低顺式聚丁二烯橡胶  凝胶  粘度  生产工艺
英文关键词: low cis-polybutadiene rubber  gel  viscosity  production process
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Author NameAffiliationE-mail
CHEN Anli* Rubber Operation Department of Dushanzi Petrochemical Company,PetroChina chenal_dbxj@petrochina.com.cn 
ZHANG Jie Rubber Operation Department of Dushanzi Petrochemical Company,PetroChina  
LIU Jide Rubber Operation Department of Dushanzi Petrochemical Company,PetroChina  
MA Jingfeng Rubber Operation Department of Dushanzi Petrochemical Company,PetroChina  
LI Shicheng Rubber Operation Department of Dushanzi Petrochemical Company,PetroChina  
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中文摘要:
      分析低顺式聚丁二烯橡胶生产过程中凝胶产生的原因,并提出相应的控制措施。通过采取控制聚合釜内杂质含量、适当提高溶剂用量、采用新型高效抗氧剂体系、控制汽提单元胶粒水的pH值在6~9、控制偶联剂加入时间及优化后处理干燥设备运行参数等措施,降低了凝胶含量,提高了产品质量,实现了生产装置长周期平稳运行。
英文摘要:
      The causes of gel formation during production of low cis-polybutadiene rubber were analyzed,and corresponding control measures were proposed.By implementing measures such as controlling impurity content in the polymerization reactor,appropriately increasing solvent dosage,adopting a new high-efficiency antioxidant system,maintaining the pH value of the latex slurry in the stripping unit between 6 and 9,controlling the adding time of coupling agent,and optimizing the operating parameters of the post-processing drying equipment,the gel content was reduced,product quality was improved,and stable long-term operation of the production unit was achieved.
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