阻燃协效剂对PVC/PNBR共混型热塑性弹性体性能的影响 |
Influence of flame-retardant synergist on properties of PVC/PNBR TPE |
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DOI: |
中文关键词: PVC 粉末丁腈橡胶 热塑性弹性体 氢氧化镁 阻燃协效剂 |
英文关键词: PVC PNBR TPE magnesium hydroxide flame retardant synergist |
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中文摘要: |
以PVC和粉末丁腈橡胶(PNBR)为主体材料,氢氧化镁为阻燃剂,制备PVC/PNBR共混型热塑性弹性体,研究阻燃协效剂三氧化二锑、硼酸锌、七钼酸铵、氧化锌和二氧化锰对弹性体性能的影响。结果表明,当PVC、PNBR、邻苯二甲酸二辛酯和氢氧化镁的用量分别为77,23,50和31份时,PVC/PNBR共混型热塑性弹性体性能良好;氢氧化镁的用量对弹性体氧指数基本无影响;在弹性体中分别单独使用4.6,6.2,1.5和6.2份三氧化二锑、硼酸锌、七钼酸铵和氧化锌时,弹性体的氧指数明显提高,综合物理性能较好,但二氧化锰协同效果不好。 |
英文摘要: |
A PVC/PNBR TPE was prepared based on PVC and powdered NBR(PNBR) using magnesium hydroxide(MH) as flame retardant,and the influence of the flame-retardant synergists,such as diantimony trioxide(Sb2O3),zinc borate(ZB),ammonium heptomolybdate(AOM),zinc oxide(ZnO) and manganese dioxide(MnO2) on the properties of above TPE was investigated.The results showed that a PVC/PNBR TPE with good properties was obtained by using 77/23 PVC/PNBR,50 phr DOP and 31 phr MH;the addition level of MH had little effect on the oxygen exponent of TPE;the oxygen exponent of TPE significantly increased and its comprehensive physical properties improved when 4.6 phr Sb2O3,6.2 phr ZB,1.5 phr AOM or 6.2 phr ZnO were respectively used in TPE;and MnO2 had little synergistic effect. |
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