文章摘要
负载钛催化体系陈化对高反式丁二烯-异戊二烯-共聚橡胶聚合转化率的影响
Effect of aging of supported titanium catalyst system on conversion ratio during polymerization of high trans-butadiene-isoprene copolymer
  
DOI：
中文关键词: 负载钛催化体系  高反式丁二烯-异戊二烯共聚橡胶  丁二烯  异戊二烯  陈化
英文关键词: supported titanium catalyst system  high trans-butadiene-isoprene copolymer  butadiene  isoprene  aging
基金项目:国家自然科学基金资助项目（20174021）；青岛市科委科学基金资助项目（02-2-kj-yj-30）
作者单位
杜凯 青岛科技大学 橡塑材料与工程教育部重点实验室 
彭杰 青岛科技大学 橡塑材料与工程教育部重点实验室 
姚薇 青岛科技大学 橡塑材料与工程教育部重点实验室 
李旭东 青岛科技大学 橡塑材料与工程教育部重点实验室 
赵永仙 青岛科技大学 橡塑材料与工程教育部重点实验室 
黄宝琛 青岛科技大学 橡塑材料与工程教育部重点实验室 
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中文摘要:
      以负载型TiCl4/MgCl2-Al（i-Bu）3为催化体系合成高反式丁二烯（Bd）-异戊二烯（Ip）共聚橡胶（TBIR），考察催化体系陈化方式和条件对聚合转化率的影响。结果表明，催化体系陈化有利于提高聚合转化率；三元陈化催化体系的聚合转化率大于二元陈化催化体系。三元陈化催化体系的优化陈化条件为：Ip/Ti摩尔比 20；Al/Ti摩尔比 20；加料顺序 TiCl4/MgCl2，Al（i-Bu）3，Ip；温度 20 ℃；时间 5～10 min。
英文摘要:
      The effect of the aging mode and condition of the supported TiCl4/MgCl2-Al（i-Bu）3 catalyst system on the conversion ratio during the polymerization of high trans-butadiene(Bd)-isoprene(Ip) copolymer(TBIR) was investigated.The results showed that the aging of catalyst system was beneficial to increase the conversion ratio during polymerization；the conversion ratio of aged ternary catalyst system was greater than that of aged binary catalyst system；and the optimized aging condition of the aged ternary catalyst system was as follows:Ip/Ti mole ratio 20，Al/Ti mole ratio 20，addition order TiCl4→MgCl2→Al（i-Bu）3→Ip，temperature 20 ℃ and time 5～10 min.
Author NameAffiliation
DU Kai Qingdao University of Science and Technology 
PENG Jie Qingdao University of Science and Technology 
YAO Wei Qingdao University of Science and Technology 
LI Xu-dong Qingdao University of Science and Technology 
ZHAO Yong-xian Qingdao University of Science and Technology 
HUANG Bao-chen Qingdao University of Science and Technology 
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