单体接枝改性炭黑填充NBR复合材料的研究 |
Properties of carbon black/NBR composite prepared by reactive modification in latex mixture |
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DOI: |
中文关键词: NBR 炭黑 单体接枝改性 复合材料 |
英文关键词: NBR carbon black monomer graft modification composite |
基金项目:国家自然科学基金资助项目(B6324440) |
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中文摘要: |
采用单体接枝改性法制备炭黑填充型NBR复合材料,并对其性能进行研究。结果表明,在NBR胶乳与炭黑的混合体系中加入适当的单体M[丙烯酸丁酯(BA)或甲基丙烯酸甲酯(MMA)]和引发剂,可以使单体M与NBR分子链发生接枝反应的同时也与炭黑表面的活性基团发生反应,从而制备NBR/M/炭黑复合材料,采用该方法制备的NBR/M/炭黑复合材料的炭黑分散性良好,物理性能和热稳定性优异。 |
英文摘要: |
A carbon black/NBR composite was prepared by monomer graft modification and its properties were investigated.The results showed that a carbon black/NBR composite was prepared by adding a suitable monomer M [butyl acrylate(BA) or methyl methacrylate(MMA)] and an initiator into the carbon black/NBR latex mixture to make M graft to the molecular chain of NBR and react with the active group on carbon black surface simultaneously;and the obtained composite possessed good black distribution and excellent physical properties and heat stability. |
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