SIS-g-AN热降解性能的研究 |
Study on thermal degradation of SIS-g-AN |
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DOI: |
中文关键词: 热塑性弹性体SIS 丙烯腈 接枝共聚物 热降解性能 热重分析 差示热重分析 |
英文关键词: SIS acrylnitrile graft copolymer thermal degradation thermalgravimetry differential thermogravimetry |
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中文摘要: |
采用热重分析法和差示热重分析法研究丙烯腈(AN)接枝热塑性弹性体SIS(SIS-g-AN)的热降解性能。结果得出,SIS-g-AN的平衡起始降解温度、平衡最大降解速率温度和平衡终止降解温度分别为659.17,713.94和740.05 K;热降解反应活化能为195.2 kJ·mol-1;热降解机理是Deceleration中的D3降解机理;不同质量损失率下的热寿命与温度呈线性关系。 |
英文摘要: |
The thermal degradation of SIS-g-AN was investigated by thermogravimetry and differential thermogravimetry.The results showed that the equilibrium temperatures of SIS-g-AN at degradation starting,maximum degradation rate and degradation end were 659.17,713.94 and 740.05 K respectively;the activation energy in thermal degradation process was 195.5 kJ·mol-1;the thermal degradation mechanism obeyed D3 in Deceleration;and the thermal lifetimes at various weight loss rates were linear with temperatures. |
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