| 氧化石墨烯负载氮化硼/天然橡胶复合材料的制备及性能研究 |
| Preparation and properties of boron nitride@graphene oxide natural rubber composites |
| 投稿时间:2023-08-20 修订日期:2023-08-20 |
| DOI:10.12136/j.issn.1000-890X.2024.09.0663 |
| 中文关键词: 氮化硼 氧化石墨烯 天然橡胶 导热性能 |
| 英文关键词: Preparation and Properties of Graphene Oxide Loaded Boron Nitride/NR Composites |
| 基金项目: |
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| 摘要点击次数: 838 |
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| 中文摘要: |
| 将具有良好水分散性的氧化石墨烯(GO)与高导热填料氮化硼(BN)纳米片反应,生成GO负载BN(BN@GO)导热填料,采用胶乳共混法制备BN@GO/天然胶(NR)复合材料,研究BN@GO的结构和复合材料的性能。结果表明:GO通过共价键紧紧包覆BN纳米片,改善了BN纳米片与橡胶基体之间的相容性,BN@GO更易在橡胶基体中形成导热网络结构;当填导热填料质量分数为20%时,填充BN@GO的BN@GO/NR复合材料的导热性能优异,与填充BN纳米片的NR复合材料相比,BN@GO/NR复合材料的热导率、拉伸强度和撕裂强度分别提高了48.5%,55.0%和44.5%。 |
| 英文摘要: |
| Graphene oxide(GO)with good water dispersibility was reacted with high thermal conductivity filler boron nitride(BN)nanosheets to generate GO-supported BN(BN@GO)thermal conductive filler,prepared by latex blending method BN@GO/Natural rubber(NR)composites,research BN@GO structure and properties of composites.The results showed that GO tightly coated BN nanosheets through covalent bonds,improving the compatibility between BN nanosheets and the rubber matrix,BN@GO was easier to form a thermal conductive network structure in the rubber matrix;when the mass fraction of thermal conductive filler was 20%,the filling BN@GO of BN@GO/NR composites was excellent,compared to the NR composite material filled with BN nanosheets,the thermal conductivity,tensile strength and tear strength of BN@GO/NR composites increased by 48.5%,55.0% and 44.5%,respectively. |
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