文章摘要
白炭黑/粉煤灰并用比对天然橡胶复合材料性能的影响
Effect of Silica/Coal Fly Ash Blend Ratios on Properties of NR Composites
投稿时间:2022-10-20  修订日期:2022-10-20
DOI:10.12136/j.issn.1000-890X.2024.09.0669
中文关键词: 天然橡胶  粉煤灰  白炭黑  拉伸性能  动态力学性能
英文关键词: NR  fly ash  silica  tensile property  dynamic mechanical property
基金项目:山东省重点研发计划(重大科技创新工程)项目2020CXGC010312、海洋科技协同创新中心项目(22-05-CXZX-04-04-28)
作者单位E-mail
张 林 青岛科技大学 4020030064@mails.qust.edu.cn 
徐 凯 山东华盛橡胶有限公司  
张 苏 青岛科技大学  
赵崇学 青岛科技大学  
王海桐 青岛科技大学  
林广义* 青岛科技大学 gylin666@163.com 
耿传宝 青岛科技大学  
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中文摘要:
      采用硅烷偶联剂KH-570分别接枝改性白炭黑和粉煤灰,研究白炭黑/粉煤灰并用比对天然橡胶(NR)/白炭黑/粉煤灰复合材料(以下简称NR复合材料)性能的影响。结果表明:随着粉煤灰用量的增大,NR复合材料的Payne效应明显减弱,这是因为粉煤灰的加入促进了填料(白炭黑/粉煤灰体系)在橡胶基体中的分散;NR复合材料的拉伸强度和拉断伸长率先增大后减小,当白炭黑/粉煤灰并用比为30/10时,NR复合材料的拉伸强度最大,80 ℃×72 h热空气老化后的拉断伸长率保持率较大;NR复合材料0 和60 ℃时的损耗因子减小,抗湿滑性能和滚动阻力降低。
英文摘要:
      Using silane couple agent to graft modified silica and coal fly ash separatly,the effect of silica/coal fly ash blend ratios on the properties of natural rubber(NR)/silica/coal fly ash composites was studied.The results showed that,as the increasing of coal fly ash amount,the Payne effect of NR composite was significantly weakened,this was because coal fly ash promoted the dispersion of filler(silica/coal fly ash system) in rubber matrix.As the increasing of coal fly ash amount,the tensile strength and elongation at break of NR composite first increased and then decreased.When the silica/coal fly ash blend ratio was 30/10,the tensile strength of NR composite was the highest,and the elongation at break retention rate after 80 ℃×72 h heat air aging was larger.As the increasing of coal fly ash amount,the loss factors at 0 and 60 ℃ of NR composite decreased,and the wet sliding resistance and rolling resistance decreased.
Author NameAffiliationE-mail
ZHANG Lin Qingdao University of Science and Technology 4020030064@mails.qust.edu.cn 
XU Kai Shandong Huasheng Rubber Co., Ltd.  
ZHANG Su Qingdao University of Science and Technology  
Zhao Chongxue Qingdao University of Science and Technology  
Wang Haitong Qingdao University of Science and Technology  
Lin Guangyi Qingdao University of Science and Technology gylin666@163.com 
GENG Chuanbao Qingdao University of Science and Technology  
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