三元乙丙橡胶J-4090和6950C的结构与性能研究 |
Study on Structures and Properties of EPDM J-4090 and 6950C |
投稿时间:2021-12-13 修订日期:2021-12-13 |
DOI:10.12136/j.issn.1000-890X.2023.04.0272 |
中文关键词: 三元乙丙橡胶 海绵密封条 密实胶 发泡胶 微观结构 物理性能 发泡特性 挤出胀大比 |
英文关键词: EPDM sponge sealing strip dense compound foamed compound microstructure physical property foaming characteristic extrusion swell ratio |
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中文摘要: |
研究2种应用于汽车海绵密封条的牌号为J-4090和6950C的三元乙丙橡胶(EPDM)的微观结构及其复合材料(包括密实胶和发泡胶)的性能。结果表明:与EPDM 6950C相比,EPDM J-4090的乙烯基质量分数较大,第三单体(亚乙基降冰片烯)质量分数较小,相对分子质量分布较宽;与EPDM 6950C密实胶相比,EPDM J-4090密实胶的硫化速率和交联密度较小,抵抗变形的能力较差,硫化体系用量增大20%的EPDM J-4090密实胶的物理性能达到EPDM 6950C密实胶一致的水平。与EPDM 6950C发泡胶相比,硫化剂和促进剂用量增大20%的EPDM J-4090发泡胶的挤出膨胀比略大,发泡特性和物理性能相近。 |
英文摘要: |
The microstructures of two brands of EPDM(J-4090 and 6950C) used in automobile sponge
sealing strips and the properties of their composites(including dense compound and foamed compound)
were studied. The results showed that,compared with EPDM 6950C,EPDM J-4090 had larger vinyl mass
fraction,smaller mass fraction of the third monomer(ethylidene norbornene) and wider molecular weight
distribution. Compared with EPDM 6950C dense compound,EPDM J-4090 dense compound had lower
vulcanization rate and crosslinking density,and poor resistance to deformation. However,when the amount
of the vulcanization system in EPDM J-4090 dense compound increased by 20%,its physical properties
could reach the same level as that of EPDM 6950C dense compound. Compared with EPDM 6950C foamed
compound,the extrusion swell ratio of the EPDM J-4090 foamed compound with 20% increase in the amount
of the vulcanization system was slightly larger,and the foaming characteristics and physical properties were
similar. |
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