文章摘要
三元乙丙橡胶J-4090和6950C的结构与性能研究
Study on Structures and Properties of EPDM J-4090 and 6950C
投稿时间:2021-12-13  修订日期:2021-12-13
DOI:10.12136/j.issn.1000-890X.2023.04.0272
中文关键词: 三元乙丙橡胶  海绵密封条  密实胶  发泡胶  微观结构  物理性能  发泡特性  挤出胀大比
英文关键词: EPDM  sponge sealing strip  dense compound  foamed compound  microstructure  physical property  foaming characteristic  extrusion swell ratio
基金项目:
作者单位E-mail
靳紫昊 北京化工大学 北京市新型高分子材料制备与加工重点实验室 1220825820@qq.com 
邹 华* 北京化工大学 北京市新型高分子材料制备与加工重点实验室 zouhua@mail.buct.edu.cn 
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中文摘要:
      研究2种应用于汽车海绵密封条的牌号为J-4090和6950C的三元乙丙橡胶(EPDM)的微观结构及其复合材料(包括密实胶和发泡胶)的性能。结果表明:与EPDM 6950C相比,EPDM J-4090的乙烯基质量分数较大,第三单体(亚乙基降冰片烯)质量分数较小,相对分子质量分布较宽;与EPDM 6950C密实胶相比,EPDM J-4090密实胶的硫化速率和交联密度较小,抵抗变形的能力较差,硫化体系用量增大20%的EPDM J-4090密实胶的物理性能达到EPDM 6950C密实胶一致的水平。与EPDM 6950C发泡胶相比,硫化剂和促进剂用量增大20%的EPDM J-4090发泡胶的挤出膨胀比略大,发泡特性和物理性能相近。
英文摘要:
      The microstructures of two brands of EPDM(J-4090 and 6950C) used in automobile sponge sealing strips and the properties of their composites(including dense compound and foamed compound) were studied. The results showed that,compared with EPDM 6950C,EPDM J-4090 had larger vinyl mass fraction,smaller mass fraction of the third monomer(ethylidene norbornene) and wider molecular weight distribution. Compared with EPDM 6950C dense compound,EPDM J-4090 dense compound had lower vulcanization rate and crosslinking density,and poor resistance to deformation. However,when the amount of the vulcanization system in EPDM J-4090 dense compound increased by 20%,its physical properties could reach the same level as that of EPDM 6950C dense compound. Compared with EPDM 6950C foamed compound,the extrusion swell ratio of the EPDM J-4090 foamed compound with 20% increase in the amount of the vulcanization system was slightly larger,and the foaming characteristics and physical properties were similar.
Author NameAffiliationE-mail
JIN Zihao Beijing University of Chemical Technology 1220825820@qq.com 
ZOU Hua Beijing University of Chemical Technology zouhua@mail.buct.edu.cn 
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