文章摘要
液体聚异戊二烯橡胶对天然橡胶/反式聚异戊二烯橡胶并用胶性能的影响
Effect of LIR on Properties of NR/TPI Blends
投稿时间:2021-04-23  修订日期:2021-04-23
DOI:10.12136/j.issn.1000-890X.2022.09.0659
中文关键词: 液体聚异戊二烯橡胶  天然橡胶  反式聚异戊二烯橡胶  硫化特性  结晶性  物理性能  动态力学性能
英文关键词: LIR  NR  TPI  vulcanization characteristics  crystallinity  physical property  dynamic mechanical property
基金项目:
作者单位E-mail
吴友平* 北京化工大学 北京市新型高分子材料制备与成型加工重点实验室 wuyp@mail.buct.edu.cn 
刘欢欢 北京化工大学 北京市新型高分子材料制备与成型加工重点实验室  
庞 松 北京化工大学 北京市新型高分子材料制备与成型加工重点实验室  
于 洋 北京化工大学 北京市新型高分子材料制备与成型加工重点实验室  
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中文摘要:
      研究液体聚异戊二烯橡胶(LIR-50)用量对未填充和填充填料的天然橡胶(NR)/反式聚异戊二烯橡胶(TPI)(并用比85/15)并用胶硫化特性、结晶性、物理性能和动态力学性能的影响。结果表明:NR/TPI并用胶的t10t90随着LIR-50用量的增大而延长,且加工流动性变好;在NR/TPI并用胶中TPI的结晶受到抑制,LIR-50用量对NR/TPI并用胶的结晶性影响不大;随着LIR-50用量的增大,NR/TPI并用胶的邵尔A型硬度、300%定伸应力、拉伸强度及储能模量减小;加入3份LIR-50的并用胶的撕裂强度最大、综合物理性能较好;LIR-50加入对NR/TPI并用胶的耐磨性能、抗湿滑性能以及滚动阻力基本无影响。
英文摘要:
      The effects of the amount of liquid polyisoprene rubber (LIR-50 ) on the vulcanization characteristics,crystallinity,physical properties and dynamic mechanical properties of the unfilled and filled NR/TPI(85/15 of blend ratio) blends were studied. The results showed that,the t10 and t90 of the NR/TPI blends were extended with the increase of the amount of LIR-50,and the processing fluidity became better. The crystallization of TPI in the NR/TPI blend was inhibited,and the amount of LIR-50 had little effect on the crystallinity of the NR/TPI blends. With the increase of the amount of LIR-50,the Shore A hardness, tensile stress at 300% elongation,tensile strength and storage modulus of the NR/TPI blends decreased. The NR/TPI blends with 3 phr LIR-50 had the largest tear strength and better comprehensive physical properties. The addition of LIR-50 had little effect on the wear resistance,wet skid resistance and rolling resistance of the NR/TPI blends.
Author NameAffiliationE-mail
WU Youping Beijing University of Chemical Technology wuyp@mail.buct.edu.cn 
LIU Huanhuan Beijing University of Chemical Technology  
PANG Song Beijing University of Chemical Technology  
YU Yang Beijing University of Chemical Technology  
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