功能化还原氧化石墨烯/天然橡胶导热复合材料的性能研究 |
Study on Properties of Functionalized Reduced Graphene Oxide/NR Thermally Conductive Composites |
投稿时间:2020-10-27 修订日期:2020-11-10 |
DOI:10.12136/j.issn.1000-890X.2021.03.0163 |
中文关键词: 氧化石墨烯 还原氧化石墨烯 功能化 天然橡胶 复合材料 导热性能 拉伸强度 |
英文关键词: GO rGO functionalization NR composite tensile strength thermal conductivity |
基金项目:山西省科技重大专项项目(20181101010) |
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中文摘要: |
采用2-巯基苯并咪唑(防老剂MB,以下简称MB)对GO进行还原及功能化,同时与采用抗坏血酸(VC)对GO进行还原以比,分别制得MB还原氧化石墨烯(rGO-MB)和VC还原氧化石墨烯(rGO-VC),并采用胶乳共混法制备rGO-MB/NR和rGO-VC/NR复合材料,对其性能进行研究。结果表明:MB成功还原了GO,MB接枝到了GO上;与rGO-VC/NR复合材料相比,rGO-MB/NR复合材料具有较低的Panye效应和较高的结合胶含量,拉伸强度和导热性能均明显提高。 |
英文摘要: |
In this study,graphene oxide (GO)was reduced and functionalized by using 2-
mercaptobenzimidazole(antioxidant MB,hereinafter referred to as MB)and ascorbic acid(VC),respectively.
Natural rubber (NR) composites filled with MB reduced graphene oxide (rGO-MB) and VC reduced
graphene oxide (rGO-VC) were prepared by latex blending method,and their properties were studied.
The results showed that,GO was successfully reduced and grafted by MB. Compared with rGO-VC/
NR composites,rGO-MB/NR composites had lower Payne effect,higher content of bound rubber,and
significantly improved tensile strength and thermal conductivity. |
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