预改性片层粘土在溴化丁基橡胶中的应用 |
Application of Pre-modified Lamellar Clay in BIIR |
投稿时间:2019-03-06 修订日期:2019-03-06 |
DOI:10.12136/j.issn.1000-890X.2020.03.0187 |
中文关键词: 粘土 有机改性 溴化丁基橡胶 复合材料 气密层 动态力学性能 气密性 |
英文关键词: clay organic modification BIIR composite inner liner dynamic mechanical properties air tightness |
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中文摘要: |
:研究预改性片层粘土(100份丁苯橡胶纳米复合80份粘土)在溴化丁基橡胶(BIIR)中的应用。结果表明:预改性片层粘土在BIIR中能够实现均匀的纳米分散,粘土片层与橡胶分子链的作用力增强;与未加预改性片层粘土的胶料相比,预改性片层粘土/BIIR复合材料的交联密度减小,正硫化时间缩短,拉伸强度、拉断伸长率和拉断永久变形增大,60 ℃时的损耗因子减小,气密性明显提高,其具有很高的性价比。 |
英文摘要: |
The application of pre-modified lamellar clay[SBR/clay (dosage ratio 100/80 )nanocomposite] in brominated butyl rubber (BIIR) was studied. The results showed that,uniform nano
dispersion of the pre-modified lamellar clay in BIIR was achieved,and the interaction force between the lamellar clay and rubber molecular chain increased. Compared with the compound without the pre-modified lamellar clay,the crosslinking density of the pre-modified lamellar clay/BIIR composite decreased,the optimum curing time was shortened,the tensile strength,elongation at break and permanent deformation at break increased,the loss factor at 60 ℃ decreased,the air tightness was significantly improved.The composite
had a high performance cost ratio. |
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