文章摘要
乳聚丁苯橡胶/白炭黑/偶联剂体系挤出流变特性的研究
Investigation on Rheological Properties of SBR/Silica/Silane Compound during Extrusion
  
DOI：
中文关键词: 乳聚丁苯橡胶  白炭黑  硅烷偶联剂  挤出流变特性  挤出温度
英文关键词: ESBR  silica  silane coupling agent  extrusion rheological behavior  extrusion temperature
基金项目:
作者单位
时金凤 青岛科技大学 橡塑材料与工程教育部重点实验室 
李建 青岛科技大学 橡塑材料与工程教育部重点实验室 
孙翀 青岛科技大学 橡塑材料与工程教育部重点实验室 
丁兴伟 青岛科技大学 橡塑材料与工程教育部重点实验室 
张萍 青岛科技大学 橡塑材料与工程教育部重点实验室 
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中文摘要:
      研究白炭黑含量和偶联剂种类对填充乳聚丁苯橡胶挤出流变特性的影响，并分析了三种偶联剂的接枝效率。结果表明：在低剪切速率下，白炭黑填充体系的非牛顿指数与其用量关系不大；在高剪切速率下，胶料的非牛顿指数随白炭黑用量增大而增大；当白炭黑用量为40份时，偶联剂Si747胶料粘度大，Payne效应明显，挤出物外观粗糙，有较好的挤出温度稳定性；偶联剂Si69与Si75对白炭黑的改性效果差别不大。
英文摘要:
      The effects of silica content and silane coupling agents on the rheological properties of filled ESBR during extrusion were investigated，and the grafting efficiency of the 3 kinds of silane coupling agents was analyzed. The results showed that the non-Newton index of silica filled system was independent on its content at low shear rate. However，the non-Newton index of this system increased with the increasing of silica content at high shear rate. When the silica content was 40 phr，the viscosity and Payne effect of silica/Si747 compound was the highest，and the appearance of extrudate was rough. However，the extrusion temperature stability was better. The modification effects of Si69 and Si75 on silica were not significantly different.
Author NameAffiliation
SHI Jinfeng Qingdao University of Science and Technology 
LI Jian Qingdao University of Science and Technology 
SUN Chong Qingdao University of Science and Technology 
DING Xingwei Qingdao University of Science and Technology 
ZHANG Ping Qingdao University of Science and Technology 
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