天然橡胶/炭黑/二硫化钼复合材料的制备和性能研究 |
Preparation and Properties of NR/Carbon Black/ Molybdenum Disulfide Composites |
投稿时间:2018-12-27 修订日期:2018-12-27 |
DOI:10.12136/j.issn.1000-890X.2019.09.0650 |
中文关键词: 二硫化钼 天然橡胶 炭黑 复合材料 分散 耐磨性能 动态力学性能 |
英文关键词: molybdenum disulfide NR carbon black composite dispersion wear resistance dynamic mechanical property |
基金项目:国家自然科学基金资助项目(21572021) |
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中文摘要: |
采用超声粉碎法制备二硫化钼(MoS2)纳米碎片,以不同用量的MoS2(纳米碎片)等量替代天然橡胶(NR)/炭黑(CB)复合材料中部分CB,制得NR/CB/MoS2复合材料,研究不同用量MoS2等量替代部分CB对复合材料Payne效应、硫化特性、物理性能、耐磨性能和动态力学性能的影响。结果表明:少量MoS2等量代替部分CB有助于复合材料中填料分散,MoS2用量过大则使填料又趋于聚集;少量MoS2等量代替部分CB会减弱复合材料的Payne效应,有利于提高复合材料的物理性能和耐磨性能,但对复合材料的滚动阻力和抗湿滑性能影响较小;过量MoS2等量代替部分CB,则其对复合材料的补强能力减弱,甚至导致复合材料性能下降。 |
英文摘要: |
Molybdenum disulfide(MoS2) nanoparticles were obtained by ultrasonic method,and the natural rubber(NR)/carbon black(CB)/MoS2 composites were prepared by using MoS2 nanoparticles to replace equal amount of CB in the NR/CB composites. The influence of MoS2 on the Panye effect,vulcanization characteristics,physical properties,wear resistance and dynamic mechanical properties of the composites was investigated. The results showed that adding a small amount of MoS2 could improve the filler dispersion. However,when the amount of MoS2 increased,the fillers tended to aggregate again. Payne effect of the composites was weakened by using a small amount of MoS2,the physical properties and wear resistance were enhanced,and the rolling resistance and wet-slip resistance of the composites were only slightly affected. When the amount of MoS2 increased to a large number,the reinforcement was weakened,and the performance of the composites deteriorated. |
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