十八胺改性氧化石墨烯/乳聚丁苯橡胶复合材料的结构与性能研究 |
Structure and Properties of Octadecylamine Modified Graphene Oxide/ ESBR Composite |
投稿时间:2018-05-30 修订日期:2018-05-30 |
DOI:10.12136/j.issn.1000-890X.2019.02.0089 |
中文关键词: 十八胺 氧化石墨烯 乳聚丁苯橡胶 复合材料 结构 动态力学性能 气密性能 |
英文关键词: octadecylamine graphene oxide ESBR composite structure dynamic mechanical property airtight property |
基金项目:国家“973”计划项目[2015CB654700(2015CB674705];国家自然科学基金资助项目(51573007);北京市科技计划课题(Z171100002217033);中央高校基本科研业务费资助项目(JD1805) |
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中文摘要: |
以十八胺(ODA)对氧化石墨烯(GO)进行改性,采用乳液复合法制备ODA功能化GO(ODA-GO)/乳聚丁苯橡胶(ESBR)复合材料,并对其结构和性能进行研究。结果表明:ODA-GO在ESBR中的分散性良好,少量ODA-GO在ESBR中能够形成较强的填料网络;与ESBR胶料相比,ODA-GO/ESBR复合材料在0 ℃时的损耗因子(tanδ)增大,60 ℃时的tanδ减小;随着ODA-GO用量的增大,复合材料的物理性能和气密性能提高。 |
英文摘要: |
The graphene oxide(GO) was modified by octadecylamine (ODA),the octadecylamine functionalized graphene oxide(ODA-GO)/emulsion styrene-butadiene rubber(ESBR) composite was prepared by emulsion composite method,and its structure and properties were studied. The results showed that,the dispersion of ODA-GO in ESBR was good,and strong filler network could be formed with small amount of ODA-GO. Compared with ESBR compound,the loss factor of ODA-GO/ESBR composite increased at 0 ℃ and decreased at 60 ℃. As the addition level of ODA-GO increased,the physical properties and airtight property of the composite were improved. |
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