文章摘要
钼系支化高乙烯基聚丁二烯橡胶动态力学性能的研究
Study on Dynamic Properties of Molybdenum-catalyzed Branched HVPBR
  
DOI：
中文关键词: 高乙烯基聚丁二烯橡胶  BR  ESBR  SSBR  动态力学性能  损耗因子
英文关键词: HVPBR  BR  ESBR  SSBR  dynamic properties  loss factor
基金项目:国家自然科学基金资助项目(50603009)
作者单位
邓志峰 青岛科技大学 橡塑材料与工程教育部重点实验室 
郭丽云 青岛科技大学 橡塑材料与工程教育部重点实验室 
徐玲 青岛科技大学 橡塑材料与工程教育部重点实验室 
华静 青岛科技大学 橡塑材料与工程教育部重点实验室 
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中文摘要:
      应用RPA2000橡胶加工分析仪研究钼系支化高乙烯基聚丁二烯橡胶(b-HVPBR)的动态力学性能，并与BR、乳聚丁苯橡胶(ESBR)和溶聚丁苯橡胶(SSBR)进行对比。结果表明：在试验频率范围内，b-HVPBR(低频下)的剪切储能模量(G′)大于BR，SSBR和ESBR，损耗模量(G″)和损耗因子(tanδ)小于BR，SSBR和ESBR，复数粘度(η*)呈现假塑性流体的特征；在试验温度范围内，b-HVPBR的G′大于BR，SSBR和ESBR， tanδ值小于BR，SSBR和ESBR；在试验应变范围内，b-HVPBR的G′大于BR，SSBR和ESBR， tanδ值小于BR，SSBR和ESBR。
英文摘要:
      The dynamic properties of molybdenum-catalyzed branched HVPBR（b-HVPBR） were studied by using rubber processing analyzer (RPA2000)，and compared with those of BR，ESBR and SSBR.The results showed that，in the range of experimental frequency，the storage modulus (G′) of b-HVPBR was the highest under low frequency，the loss modulus (G″) and loss factor ((tanδ) were smaller than those of BR，ESBR and SSBR，respectively,and their complex viscosity (η*) showed the same trait with that of pseudoplastic fluid.In the range of experimental temperature or strain，the G′ of b-HVPBR was higher than that of BR，ESBR and SSBR，and the (tanδ was smaller.
Author NameAffiliation
DENG Zhi-feng Qingdao University of Science and Technology 
GUO Li-yun Qingdao University of Science and Technology 
XU Ling Qingdao University of Science and Technology 
HUA Jing Qingdao University of Science and Technology 
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