白炭黑表面改性对NR/BR硫化胶性能的影响 |
Influence of silica surface modification on physical properties of NR/BR vulcanizate |
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DOI: |
中文关键词: 白炭黑 表面改性 偶联剂 表面活性剂 硫化胶 物理性能 老化 |
英文关键词: silica surfactant coupling agent surface modification vulcanization aging |
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中文摘要: |
研究了10种偶联剂和3种表面活性剂改性白炭黑后对NR/BR硫化胶性能的影响。试验结果表明,不同表面改性剂改性白炭黑后对NR/BR硫化胶物理性能的影响程度大小顺序为:硅烷类偶联剂>钛酸酯类偶联剂>表面活性剂。其中硅烷类偶联剂的改性效果优劣顺序为:KH-550>KH-846>KH-590>KH-560,带胺基和磷酸酯基团的偶联剂具有较好的抗老化作用;钛酸酯类偶联剂的改性效果优劣顺序为:NDZ-311w>NDZ-102>NDZ-201>NDZ-311>NDZ-401>NDZ-101;表面活性剂的改性效果优劣顺序为:ATAC>T-40>ABS。 |
英文摘要: |
The influence of the surface modification for silica with 10 types of coupling agents and 3 types of surfactants respectively on the physical properties of NR/BR vulcanizate was investigated.The results showed that the positive effects of different surface modifiers on the physical properties of NR/BR vulcanizate were as follows:silane coupling agent>titanate coupling agent>surfactant;amongsilane coupling agents,KH-550>KH-846>KH-590>KH-560,and amino group or phosphate groupcontaining coupling agents had better aging properties;among titanate coupling agents,NDZ-311w>NDZ-102>NDZ-201>NDZ-311>NDZ-401>NDZ-101;and among surfactants,ATAC>T-40>ABC. |
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