PPC/SBR共混物的研究 Ⅱ.混炼工艺对共混物性能的影响 |
Study on PPC/SBR Blend Part 2.Influence of Mixing Procedure on Blend Properties |
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DOI: |
中文关键词: 聚亚丙基碳酸酯 SBR 共混 混炼 |
英文关键词: PPC(polypropylene carbonate) SBR blend mixing |
基金项目:国家自然科学基金、中国科学院高分子物理联合开放研究实验室资助项目 |
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中文摘要: |
研究了混炼工艺对聚亚丙基碳酸酯(PPC)/SBR共混物性能的影响。结果表明,采用混炼工艺A(SBR+PPC→配合剂→陈化12 h→MA→返炼→硫化),可在提高硫化体系活性的基础上消除陈化对共混物拉伸性能的影响;将PPC与SBR预混后混炼,可提高共混物的定伸应力和硬度,降低扯断永久变形;停放时间延长(2 h以内)有利于共混物性能的提高;薄通次数增加对共混物性能无显著影响。 |
英文摘要: |
The influence of mixing procedure on the properties of PPC/SBR blend was investigated.The results showed that the aging effect on the tensile strength of PPC/SBR blend was eliminated by using the mixing procedure A(SBR+PPC→compounding ingredients→aging for 12 h→MA→remilling→curing )while the activity of curing system increased;the modulus and hardness of the blend increased,and its tensile set at break decreased as PPC/SBR blend was premixed;the better properties of the blend was beneficial from the longer conditioning time(up to 12 h);the increase of mill runs had no significant effect on the blend properties. |
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