用合成相容剂制备NBR/PP动态硫化共混型热塑性弹性体的研究 |
Dynamically-curable Thermoplastic Elastomer of NBR/PP Blend Prepared with Synthetic Compatibilizer |
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DOI: |
中文关键词: NBR PP共混 热塑性弹性体 动态硫化 |
英文关键词: NBR PP blend thermoplastic elastomer dynamically-curable |
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中文摘要: |
用马来酸酐接枝聚丙烯(MP)/胺/端羧基液体丁腈橡胶(CTBN)反应,生成PP-NBR嵌段共聚物作为相容剂制备NBR/PP动态硫化共混型热塑性弹性体效果很好,其中尤以MP/1.6己二胺/CTBN效果最为理想。相容剂用量控制在6%左右。PP的熔融指数越小,共混体的性能越好。硫化体系采用盼醒树脂2402/氯化亚锡(8/0.5)、加入一定量的增塑剂邻苯二甲酸二辛酯和补强剂高耐磨炭黑,可获得性能较好的共混体。 |
英文摘要: |
A dynamically-curable thermoplastic elastomer of NBR/PP blend was prepared with a block copolymer formed in the reaction of maleic anhydride-graft polypropylene (MP)/a amine/liquid carboxyl terminal butadiene nitrile rubber (CTBN) as compatibilizer.Among amines, hexamethylene diamine was the most efficient. The preferrable level of the compatibilizer was about 6% . The lower the melt index, the better the properties of the blend. A blend with better properties could be obtained by adding phenolic resin 2402/tin bichloride (8/0.5) curative and a certain level of dioctyl phthalate plasticizer and HAF reinforcing agent. |
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