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新型耐迁移大分子防老剂BH-F77在天然橡胶中的应用性能研究
Study on Application Performance of a New Type of Migration Resistant Macromolecular Antioxidant BH-F77 in NR
Received:May 21, 2024  Revised:May 21, 2024
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中文关键词: 耐迁移大分子防老剂;天然橡胶;耐臭氧老化性能;耐迁移性能
英文关键词: migration resistant macromolecular antioxidan;NR;ozone aging property;migration resistance property
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Author NameAffiliationE-mail
WANG Qiaoping Qingdao Doublestar Tire Industry Co.,Ltd 17863934916@163.com 
HUANG Yigang* Qingdao Doublestar Tire Industry Co.,Ltd hyg769@163.com 
WANG Jun Qingdao Doublestar Tire Industry Co.,Ltd  
ZHAO Xiaodong Qingdao Doublestar Tire Industry Co.,Ltd  
ZHANG Jing Qingdao Doublestar Tire Industry Co.,Ltd  
WANG Ziqi Qingdao Doublestar Tire Industry Co.,Ltd  
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中文摘要:
      研究新型耐迁移大分子防老剂BH-F77(简称防老剂BH-F77)在天然橡胶(NR)中的应用。结果表明:与传统防老剂6PPD相比,防老剂BH-F77的相对分子质量较高,热稳定性较好,金属元素种类较多且含量较高,耐迁移性能较优且不易变色;随着防老剂BH-F77用量的增大,NR胶料的流动性和加工安全性变差,硫化速度加快,硫化胶的邵尔A型硬度和100%定伸应力增大,拉伸强度和拉断伸长率减小,耐臭氧老化性能下降。
英文摘要:
      The application performance of a new type of migration resistant macromolecular antioxidant BH-F77(abbreviation antioxidant BH-F77)in natural rubber(NR) was studied.The results showed that compared with traditional antioxidant 6PPD,antioxidant BH-F77 had a higher relative molecular weight,better thermal stability,more types and contents of metal elements,better migration resistance and less discoloration.As the dosage of antioxidant BH-F77 increased,the flowability and processing safety of NR compound were deteriorated,the vulcanization rate was accelerated,the Shore A hardness and modulus at 100% of the vulcanizate increased,the tensile strength and elongation at break reduced and the ozone aging resistance decreased.
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