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炭黑氧化度对顺丁橡胶/天然橡胶并用胶性能的影响 |
Effect of Carbon Black Oxidation Degree on Properties of BR/NR Blend |
Received:February 01, 2023 Revised:February 01, 2023 |
DOI:10.12135/j.issn.1006-8171.2024.07.0418 |
中文关键词: 顺丁橡胶;天然橡胶;炭黑;氧含量;Payne效应 |
英文关键词: |
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Author Name | Affiliation | E-mail | WANG Haiyan* | Qingdao Black Cat Carbon Black Technology Co., Ltd | haiyan756com@163.com | WU Jiachen | Qingdao Black Cat Carbon Black Technology Co., Ltd | | WANG Xun | Qingdao Black Cat Carbon Black Technology Co., Ltd | |
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中文摘要: |
研究炭黑氧化度对顺丁橡胶(BR)/天然橡胶(NR)并用胶性能的影响。经高温脱挥或氧化处理后炭黑填充的BR/NR并用胶的门尼粘度增大,加工性能变差;与未处理的炭黑填充BR/NR并用胶相比,高温脱挥处理炭黑填充BR/NR并用胶的300%定伸应力、拉伸强度和压缩疲劳温升提高,耐老化性能降低;随着炭黑氧化度的增大,BR/NR并用胶的300%定伸应力、拉伸强度、撕裂强度和压缩疲劳温升降低;随着炭黑挥发分含量和氧化度的减小,0和60 ℃时BR/NR并用胶的损耗因子增大。 |
英文摘要: |
The effect of carbon black oxidation degree on the properties of butadiene rubber(BR)/natural rubber(NR) blends was studied.The Mooney viscosity of BR/NR blend filled with carbon black after treatment by high-temperature devolatilization or oxidation increased,and the processing performance deteriorated.Compared with untreated carbon black filled BR/NR blends,the high temperature devolatilization treated carbon black filled BR/NR blends showed an increase in modulus at 300% elongation,tensile strength and compressive fatigue temperature-rise increased,while the aging resistance decreased.As the oxidation degree of carbon black increased,the 300% tensile stress,tensile strength,tear strength and compressive fatigue temperature-rise of BR/NR blend decreased.As the volatile content and oxidation degree of carbon black decreased,the loss factor of BR/NR blend increased at 0 and 60 ℃. |
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